I don't think there are any definitive rules - there is so much flexibility and creative potential :-)
But, here is a suggested basic 'start with' list :
1. Switch from full to 'pre' amp model.
2. Think in mono! The DT is a mono amp, so dual amp patches, stereo effects, etc aren't going to sound the same.
3. Centre the mixer channels. i.e. both at 50% (or set channel A to 50% and mute channel B if you aren't using dual paths).
4. Having switched to a 'pre' amp model, you have probably lost your original tone (back to defaults), so mute your effects, set the DT topology you want, then adjust the tone controls and gain and volume settings. You might want to record your studio direct tones before you start, so you have reference tones (I suggest two recordings for each patch, one with effects on and the other with all the effects muted).
5. Then individually adjust each effect - again these sound quite different through the power section of the DT.
The amp models and effects respond very differently when put through the DT (compared to studio direct), particularly at volume, so you need to do 4) and 5) at your gig volume level.
I've found this process takes time, but after a while it becomes instinctive, as you get more of a feel to how the amp responds. Taking regular breaks to rest your ears also helps.
Hope that helps. Enjoy!